About the Chemical PE Exam

Advice from Previous Examinees


The Chemical PE exam is an 8-hour, all-objective test. It is administered in two four-hour sections with a break for lunch. The exam consists of a total of 80 multiple-choice questions, and examinees must work all of them.

Official Exam Topics (as of April 2003)

Note: NCEES states that the knowledge areas specified A, B, C, etc., are examples of kinds of knowledge, but they are not exclusive or exhaustive categories.
  1. Mass/Energy Balances and Thermodynamics: approx. 24% of problems
    1. Mass Balances: approx. 11% of problems
      • Material balances and stoichiometry
      • Phase behavior
      • Process variants: bypass, recycle, purge
      • Combustion processes (e.g., water-free analysis,e xcess air, staged combustion)
    2. Energy Balances and Thermodynamics: approx. 13% of problems
      • Sensible heat (heat capacity)
      • Latent heat (e.g., fusion, vaporization, sublimation)
      • Heat of reaction (exothermic, endothermic)
      • Heat of solution
      • Estimation and correlation of physical properties
      • Applications requiring combinations of sensible heat calculations, latent heat considerations, heats of reaction, etc.

  2. Fluids: approx. 17% of problems
    1. Fluid Transport: approx. 3% of problems
      • Physical properties (e.g., viscosity, density, surface tension)
      • Pipe and tubing data (e.g., schedule number, surface roughness)
    2. Mechanical/Energy Balance: approx. 11% of problems
      • Potential (e.g., elevation change) and kinetic energy (e.g., velocity)
      • Friction: Reynolds number
      • Friction: pressure drop (e.g., friction factor, pipes, valves, fittings, expansion and contraction)
      • Flow applications: single conduit, parallel and branched systems
      • Flow applications: pumps, turbines, and compressors (e.g., work/energy requirements, efficiency and performance curves)
      • Flow applications: two-phase flow (e.g., slug flow)
      • Flow applications: filtration
    3. Flow Measurement Techniques: approx. 3% of problems
      • Pitot tube, orifice, and venturi, etc.
      • Pressure differential measurement (e.g., manometers)
      • Mass flow (e.g., Coreolis, vortex shedding, thermal)
      • Permanent pressure drop (e.g., orifice, valve)

  3. Heat Transfer: approx. 16% of problems
    1. Mechanisms: approx. 6% of problems
      • Physical properties (viscosity, density, heat capacity, etc.)
      • Conduction (e.g., Fourier's Law in differential and integral form, parallel and series arrangements, mean area)
      • Convection: free (natural) convective heat-transfer coefficient
      • Convection: forced convective heat-transfer coefficient (metallic and nonmetallic)
      • Phase change (e.g., vaporization, condensation, sublimation, crystallization)
      • Combinations of mechanisms: (conduction, convection, and radiation in series)
    2. Applications: approx. 10% of problems
      • Insulation (e.g., type, sizing, and placement)
      • Measurement instruments (thermocouples, thermometers, RTD, IR, etc.)
      • Heat exchangers: overall heat-transfer coefficient, fouling factors, Reynolds numbers
      • Heat exchangers: mean temperature difference (LMTD, f-factor)
      • Heat exchangers: types (e.g., double pipe, shell-and-tube, extended surface, plate)
      • Heat exchangers: design (e.g., area, configuration, pressure drop)
      • Heat exchangers: evaluation of existing and new exchanger systems (NTU method/pinch technology)
      • Service use of heat transfer equipment (e.g., condensers, reboilers, heat pumps)
      • Radiant and convective transfer

  4. Mass Transfer: approx. 13% of problems
    1. Phase Equilibria: approx. 5% of problems
      • Equilibrium data (e.g., VLE, LLE): equations of state
      • Equilibrium data (e.g., VLE, LLE): Henry's Law and Raoult's Law
      • Equilibrium data (e.g., VLE, LLE): non-ideal solutions (e.g., activity coefficient)
      • Equilibrium data (e.g., VLE, LLE): azeotrope systems
      • Phase equilibrium calculations: bubble and dew points
      • Phase equilibrium calculations: flash calculation
      • Diffusion (e.g., purification, water treatment, chip manufacturing, chemical vapor deposition)
    2. Mass Transfer Contactors (absorptions, stripping, distillation, extraction): approx. 7% of problems
      • Continuous contacting (packed): minimum rate of flow of liquid (absorption), vapor (stripping), solvent (extraction) and reflux (distillation)
      • Continuous contacting (packed): minimum number of transfer units or stages
      • Continuous contacting (packed): height and number of transfer units or stages
      • Continuous contacting (packed): types of packing
      • Continuous contacting (packed): flooding?calculation of minimum vessel diameter
      • Continuous contacting (packed): feed location for distillation column/tower
      • Trayed contactors: minimum rate of flow of liquid (absorption), vapor (stripping), solvent (extraction), and reflux (distillation)
      • Trayed contactors: minimum number of stages
      • Trayed contactors: theoretical stages?graphical methods
      • Trayed contactors: flooding?calculation of minimum vessel diameter
      • Trayed contactors: stage efficiency
      • Trayed contactors: feed location for distillation column/tower
    3. Miscellaneous Separation Processes: approx. 1% of problems
      • Drying
      • Adsorption (e.g., PSA, water treatment)

  5. Kinetics: approx. 11% of problems
    1. Reaction Parameters: approx. 2% of problems
      • Rate constant
      • Chemical equilibria
      • Activation energy
    2. Reaction Rate: approx. 2% of problems
      • Rate equation
      • Order of reaction
      • Analysis of experimental data from reaction systems
    3. Reactor Design and Evaluation: approx. 5% of problems
      • Batch reactor
      • Continuous stirred-tank reactor to include recycle to the reactor
      • Plug-flow reactor (e.g., gas phase reactor)
      • Multiple reactors in series
      • Yield and selectivity
    4. Heterogeneous Reaction Systems: approx. 2% of problems
      • Multi-phase reactors: fluidized beds
      • Multi-phase reactors: packed beds
      • Stability/runaway reactions
      • Mixing

  6. Plant Design and Operation: approx. 19% of problems
    1. Economic Consideration: approx. 2% of problems
      • Equipment-cost correlations (e.g., cost indices)/economic calculations
      • Operating costs
      • Time value of money
    2. Design and Operation: approx. 6% of problems
      • Process equipment design
      • Process flow sheet development
      • Design optimization
      • Operating manuals (e.g., startup, shutdown, maintenance)
      • Equipment testing, troubleshooting, and analysis
    3. Safety: approx. 5% of problems
      • Emergency venting devices (e.g., safety valves, blowout walls)
      • Performance of scheduled audits (e.g., testing safety valves, checking rupture, disks)
      • Flares and vents
      • Plant layout considerations (e.g., equipment arrangement, pipe racks, and layouts)
      • Fire protection
      • Emergency ingress and egress
      • Process hazard analysis
    4. Environmental: approx. 2% of problems
      • Evaluation and permitting of gas discharges and liquid discharges
      • Solid waste management (non-hazardous and hazardous)
      • Industrial hygiene (e.g., MSDS, TLV, noise control, ventilation, personal protective equipment)
      • Pollution prevention
    5. Materials: approx. 2% of problems
      • Materials properties and selection
      • Structural design considerations (e.g., temperature limits, pressure limits, thermal expansion, pressure vessels per ASME Section VIII)
      • Corrosion considerations
    6. Process Control: approx. 2% of problems
      • Sensors (e.g., choice, location)
      • Controller actions
      • Feed-back/feed-forward actions
      • Data interpretation
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